The Bromination of benzene involves the introduction of a bromine atom onto the benzene ring through electrophilic aromatic substitution. A Lewis acid typically catalyzes the reaction, often iron (III) chloride (FeCl3). Here is the reaction with a concise explanation: Here is a step-by-step mechanism for the bromination of benzene: Step 1: Formation of electrophile: The … Read more
Introduction: The chlorination of benzene involves the introduction of a chlorine atom onto the benzene ring through electrophilic aromatic substitution. A Lewis acid typically catalyzes the reaction, often iron (III) chloride (FeCl3). Here is the reaction with a concise explanation: Here is a step-by-step mechanism for the chlorination of benzene: Step 1: Formation of electrophile: … Read more
Introduction: Aromatic halogenation reactions involve the introduction of halogen atoms (fluorine, chlorine, bromine, or iodine) into an aromatic ring. These reactions are a subset of electrophilic aromatic substitution (EAS) reactions, where a halogen replaces a hydrogen atom on the aromatic ring. Here’s an overview of the general mechanism and examples of aromatic halogenation reactions: Mechanism … Read more
Introduction: Electrophilic aromatic substitution reactions are a category of organic reactions in which an electrophile displaces an atom bonded to an aromatic ring. Typically, these reactions entail the substitution of a hydrogen atom within a benzene ring with an electrophile. In electrophilic aromatic substitution, the aromaticity of the ring remains intact. For instance, the formation … Read more
Aromaticity in organic chemistry describes the enhanced stability and unique properties of certain cyclic compounds with a specific pi-electron arrangement. The Huckel Rule, formulated by Erich Huckel in the 1930s, provides a quantitative criterion for determining whether a compound exhibits aromatic characteristics. Key Concepts of Aromaticity: 1. Planarity: Aromatic compounds are typically planar, with all … Read more
Benzene, a six-carbon ring with alternating double bonds, exhibits unique chemical stability compared to aliphatic compounds. Its reactions often involve substitution rather than addition reactions. Here are some fundamental chemical reactions of benzene: 1. Substitution Reactions: (a) Halogenation: Benzene can undergo halogenation in the presence of a halogen (e.g., chlorine or bromine) and a catalyst. … Read more
Benzene’s special stability is due to the delocalized π molecular orbital formation. The magnitude of this extra stability can be estimated by measuring the changes in the heat of hydrogenations associated with reactions. Hydrogenation of cyclohexane evolves 28.6 kcal/mol, a value typical for hydrogenation of alkenes. Fig makes these energy relationships more evident. The 36kcal … Read more
Introduction The structure of benzene is best described in the modern molecular orbital theory. All six carbon atoms in benzene are sp2 hybridized. The sp2 hybrid orbitals overlap with each other and with the s orbitals of the six hydrogen atoms forming C-C and C-H σ bonds. Formation of σ- bonds in benzene Since the … Read more
In the case of benzene, Kekule’s structures (1) and (2) represent the resonance structures. The actual structure of the molecule may be represented as a hybrid of these two resonance structures or by the single structural formula (3). It should be clearly understood that the resonance structures (1) and (2) are not the actual structures … Read more
Introduction: In 1865, Kekule suggested benzene consisted of a cyclic planar structure of six carbons with alternate double and single bonds. To each carbon was attached one hydrogen. Benzene, according to this proposal, was simple 1,3,5-cyclohexatriene. Kekule’s structure of benzene explained satisfactorily the following points. 1. That benzene contains three double bonds. 2. All six … Read more
